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$n_{C_xH_yCOOH}=a mol, n_{C_xH_yCOOCH_3} =b mol, n_{CH_3OH}=c mol$ $n_{CO_2}=0,12 mol,n_{H_2O}=0,1 mol,n_{NaOH}=0,03 mol,n_{CH_3OH sau pư }=0,03 mol$
$\begin{cases}C_xH_yCOOH \\ C_xH_yCOOCH_3 \\CH_3OH \end{cases} \overset{O_2}{\rightarrow} \begin{cases}n_{CO_2}=a(x+1)+b(x+2)+c=0,12 \\ \frac{a(y+1)}{ 2}+\frac{b(y+3)}{2}+\frac{4c}{2}=0,1 \end{cases}\Rightarrow \begin{cases}x(a+b)+(a+2b+c)=0,12 (1)\\ y(a+b)+(a+3b+4c)=0,2 (2)\end{cases}$
$\begin{cases}C_xH_yCOOH \\ C_xH_yCOOCH_3 \\CH_3OH \end{cases} \overset{NaOH}{\rightarrow}\begin{cases}n_{C_xH_yCOONa}=a+b=0,03 \\ n_{CH_3OH}=b+c=0,03 \end{cases}$ Thay vào $(1)\Rightarrow x=2$ $(2)\Rightarrow y(a+b)=0,2-(a+b)-2(b+c)-2c\Rightarrow y=\frac{11-200c}{3} (3)$ Mặt khác: $a(y+69)+b(y+83)+32c=2,76\Rightarrow y(a+b)+69(a+b)+14(b+c)+18c=2,76$ $\Rightarrow y=9-600c (4)$ Từ $(3),(4)\Rightarrow \frac{11-200c}{3}=9-600c\Rightarrow c=0,01\Rightarrow y=3\Rightarrow C_2H_3COOH,C_2H_3COOCH_3,CH_3OH$
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Trả lời 27-10-12 02:12 PM
viet130480
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